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Oxidative C—H and C—C Bond Cleavage by a (2,2′-Bipyridine)Copper(I) Chloride Complex

✍ Scribed by Csonka, Róbert; Kaizer, József; Giorgi, Michel; Réglier, Marius; Hajba, László; Mink, János; Speier, Gábor


Book ID
127164781
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
201 KB
Volume
47
Category
Article
ISSN
0020-1669

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tic-Diols were oxidized with aqueous hydrogen peroxide in the presence of heteropolyacids to yield carboxylic acids as main products in good yields. Although the oxidation proceeded via cw-ketol or cu-diketone intermediates, another oxidation path such as direct C-C bond cleavage is suggested in the