tic-Diols were oxidized with aqueous hydrogen peroxide in the presence of heteropolyacids to yield carboxylic acids as main products in good yields. Although the oxidation proceeded via cw-ketol or cu-diketone intermediates, another oxidation path such as direct C-C bond cleavage is suggested in the
✦ LIBER ✦
Oxidative C—H and C—C Bond Cleavage by a (2,2′-Bipyridine)Copper(I) Chloride Complex
✍ Scribed by Csonka, Róbert; Kaizer, József; Giorgi, Michel; Réglier, Marius; Hajba, László; Mink, János; Speier, Gábor
- Book ID
- 127164781
- Publisher
- American Chemical Society
- Year
- 2008
- Tongue
- English
- Weight
- 201 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0020-1669
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