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Oxidative bromination of olefins catalyzed by thallium(III) and heteropolyacids in aqueous solutions

โœ Scribed by Gorodetskaya, T. A. ;Kozhevnikov, I. V. ;Matveev, K. I.


Book ID
112689983
Publisher
Springer
Year
1981
Tongue
English
Weight
108 KB
Volume
16
Category
Article
ISSN
0133-1736

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Oxidation of thallium(I) by hexacyanofer
โœ G. S. Gokavi; J. R. Raju ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 602 KB

The hexacyanoferrate(II1)-thallium(1) reaction in aqueous acetic acid containing large concentrations of hydrochloric acid is considerably accelerated both by hydrogen and chloride ions as well as increasing acetic acid in the medium. The experimental results obey the rate law (1) where PI to p6 (1