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Oxidative aging of natural rubber vulcanizates. Part III. Crosslink scission in monosulfidic networks

โœ Scribed by T. Colclough; J. I. Cunneen; G. M. C. Higgins

Publisher
John Wiley and Sons
Year
1968
Tongue
English
Weight
722 KB
Volume
12
Category
Article
ISSN
0021-8995

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Oxidative aging of natural rubber vulcan
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โœ C. L. M. Bell; R. Tiller ๐Ÿ“‚ Article ๐Ÿ“… 1967 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 415 KB ๐Ÿ‘ 2 views

A new method has been developed for measuring the number of molecules of oxygen required ( 6 ) to cause a main chain scission in peroxide vulcanisates of natural rubber. This method is based on experimentally derived relationships and is not dependent on statistical theories of rubber elasticity. Th

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Oxidative aging of natural rubber vulcanizates. Part II. Effect of vulcanizate structure
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The oxidation characteristics of protected and unprotected vulcanizates from natural rubber have been examined. With unpurified rubber (RSS1) in the presence or absenee of added antioxidants the rate of oxidation of the VulCSnizates is: rmaccelerakd sulfur > accelerated sulfur > TMTD sulfurless or E