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Oxidative addition - reductive elimination sequences in the photochemistry of some bis(phosphine)platinum complexes

✍ Scribed by Carlo Bartocci; Andrea Maldotti; Silvana Sostero; Orazio Traverso


Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
465 KB
Volume
253
Category
Article
ISSN
0022-328X

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As part of studies aimed at delineating the mechanism of the rhodium(III) complexes 2a,b and 3a,b have been characterized by 31 P-, 1 H-, and 13 C-NMR spectrometry, as rhodium complex-catalyzed hydroamination of olefins, the model complexes [Rh(PNP)R] (R = CH 3 1a, C 6 H 5 1b) have well as by EI mas