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Oxidative addition reactions of halogens to Rh(I) complexes

โœ Scribed by M.R. Gajendragad; U. Agarwala

Book ID
115973510
Publisher
Elsevier Science
Year
1975
Weight
124 KB
Volume
37
Category
Article
ISSN
0022-1902

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โœ A.J. Blake; E.A.V. Ebsworth; J.H. Holloway; M.J. Rieland ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 29 KB

IK(I)-and Rh(I)-complexes react with CF3-halides to give oxidative addition products. In the reaction of IrX(CO)(PEt3)2 with CF31, X = Cl, Br, I, and with CF3Br, X = Cl, Br, only the tram addition products are formed.