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Oxidative-addition of thiuram disulfides to osmium(0): Synthesis of cis-[Os(CO)2(S2CNR2)2] (R = Me, Et, Cy, CH2CH2OMe) and molecular structures of cis-[Os(CO)2(S2CNMe2)2] and [(MeOCH2CH2)2NCS]2

✍ Scribed by Md. Manzurul Karim; Md. Nurul Abser; Mohammad R. Hassan; Niladri Ghosh; Helmut G. Alt; Idris Richards; Graeme Hogarth


Book ID
116843399
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
302 KB
Volume
42
Category
Article
ISSN
0277-5387

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Reaction of the activated heptaosmium cluster [Os 7 (CO) 19 made up of four tetrahedra sharing three common faces. From electrochemical studies, the extent of the cathodic (MeCN) 2 ] with 1,4-thioxane in CH 2 Cl 2 at ambient temperature led to the isolation of three air-stable clusters shifts of th