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Oxidative addition of aryl carboxylates to nickel(0) complexes involving cleavage of the acyl-oxygen bond

✍ Scribed by Yamamoto, Takakazu; Ishizu, Junichi; Kohara, Teiji; Komiya, Sanshiro; Yamamoto, Akio


Book ID
124051258
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
892 KB
Volume
102
Category
Article
ISSN
0002-7863

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Mechanism of the oxidative addition of a
✍ Jutand, Anny (author);Pytkowicz, Julien (author);Roland, Sylvain (author);Mangen πŸ“‚ Article πŸ“… 2010 πŸ› Walter de Gruyter GmbH 🌐 English βš– 400 KB

Bis-__N__-heterocyclic carbenes Pd^0^ complexes, Pd^0^(NHC)~2~, are efficient catalysts in Heck reactions performed with aryl bromides or chlorides. The Pd^0^(NHC)~2~ that are not stable are generated in situ from Pd^II^ precursors PdY~2~(NHC)~2~ (Y = halides) after a chemical reduction. The latter