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Oxidative-addition and proton-transfer reactions of fluorocarbon acids. Structures of trans-(Ph3P)2Pt(H2O)(PhC:CHPh)+HC(SO2CF3)2- and trans-(PH3P)2PtH[C-HC(SO2CF3)2]

✍ Scribed by Siedle, A. R.; Gleason, W. B.; Newmark, R. A.; Pignolet, L. H.


Book ID
126447058
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
874 KB
Volume
5
Category
Article
ISSN
0276-7333

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[2+4] and [2+2] Cycloaddition Reactions
✍ David J. Brauer; Hans Bürger; Gottfried Pawelke; Jürgen Rothe 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 German ⚖ 86 KB 👁 1 views

N-sulfinylacylamides R-C(ϭO)-NϭSϭO react with (CF 3 ) 2 BNMe 2 (1) to form, by [2ϩ4] cycloaddition, six-membered rings cyclo-(CF 3 ) 2 B-NMe 2 -S(ϭO)-NϭC(R)-O for R ϭ Me (2), t-Bu (3), C 6 H 5 (4), and p-CH 3 C 6 H 4 (5) while N-sulfinylcarbamic acid esters R-O-C(ϭO)-NϭSϭO react with 1 to yield mixt