Oxidations of hypophosphorus and arsenious acids by 12-tungstocobaltate(III) anion in aqueous solution
β Scribed by G. Adefikayo Ayoko
- Publisher
- Springer
- Year
- 1990
- Tongue
- English
- Weight
- 368 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0340-4285
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## Abstract The reaction between Sb(III) and [Co^III^W~12~O~40~]^5β^ proceeds with two, oneβelectron steps; formation of unstable Sb(IV) is the slow first step followed by its reaction with another oxidant in a fast step. The reaction rate is unaffected by the [H^+^] as there are no protonation equ
Reduction of halopentacyanocobaltate(III) anions 123
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