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Oxidation with sodium peroxide Direct introduction of a γ carbonyl group into α,β unsaturated ketosteroids

✍ Scribed by Herbert L. Holland; Ulrich Daum; Elly Riemland

Publisher: Elsevier Science
Year: 1981
Tongue: French
Weight: 98 KB
Volume: 22
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)92437-2

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✦ Synopsis

Aqueous sodium peroxide oxidises the conjugated A4-3-ketosteroids &?-,1q to the corresponding A 4-3,6-diones in good yield. Saturated carbonyl and alcohol groups are not affected by the reaction.

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