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Oxidation-reduction reactions of complexes with macrocyclic ligands. Kinetic and electrochemical studies of metal-ligand synergism

✍ Scribed by Switzer, Jay A.; Endicott, John F.; Khalifa, Mohamed A.; Rotzinger, Francois P.; Kumar, Krishan

Book ID
126033218
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
799 KB
Volume
105
Category
Article
ISSN
0002-7863

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Metal Complexes with Macrocyclic Ligands
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✍ Philipp Schultz-Grunow; Thomas A. Kaden πŸ“‚ Article πŸ“… 1978 πŸ› John Wiley and Sons 🌐 German βš– 254 KB πŸ‘ 1 views

## Abstract The complexation kinetics of the two macrocycles **1** and **2** with Co^2+^, Ni^2+^, Cu^2+^ and Zn^2+^ have been measured by pH‐stat techniques. The rates are first order in metal and ligand concentration and depend upon the pH. This results from the different reactivities of the vario