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Oxidation-reduction reactions between cobalt(II) and -(III) chelate and iron(III) and -(II) cyanide complexes. Outer- vs. inner-sphere mechanisms

✍ Scribed by Huchital, Daniel H.; Lepore, Joseph


Book ID
120823124
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
703 KB
Volume
17
Category
Article
ISSN
0020-1669

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Kinetic salt effects on the outer sphere
✍ P. LΓ“Pez; E. MuΓ±;Oz; F. SΓ‘Nchez; M. GalΓ‘n πŸ“‚ Article πŸ“… 1992 πŸ› John Wiley and Sons 🌐 English βš– 529 KB

A study is made of the kinetic salt effects upon the outer-sphere electron transfer reaction between hexacyanoferrate(I1) and 4-pyridinecarboxylatopentaamminecobalt(III~. The observed salts effects are analyzed, taking into account the possible association of the reactants with the ions of the suppo