Oxidation-reduction behavior of bianthrone and bianthronyl in basic dimethyl sulfoxide solutions
✍ Scribed by Mattar, Saba M.; Sutherland, Douglas
- Book ID
- 121278430
- Publisher
- American Chemical Society
- Year
- 1991
- Tongue
- English
- Weight
- 579 KB
- Volume
- 95
- Category
- Article
- ISSN
- 0022-3654
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## Abstract The kinetics of oxidation of dimethyl sulfoxide (DMSO) by chloramine‐T (CAT) is studied in HClO~4~ and NaOH media with OsO~4~ as a catalyst in the latter medium. In acid medium, the rate law is ‐__d__ [CAT]/__dt__ = __k__ [CAT][DMSO][H^+^]. Alkali retards the reaction and the rate law t