Oxidation of Zeise's Salt by [PtCl6]2-: A Mechanistic Model for Hydrocarbon Oxidation
β Scribed by Luinstra, Gerrit A.; Wang, Lin; Stahl, Shannon S.; Labinger, Jay A.; Bercaw, John E.
- Book ID
- 121273536
- Publisher
- American Chemical Society
- Year
- 1994
- Tongue
- English
- Weight
- 216 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0276-7333
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The reaction kinetics of the reactions of Hantzsch esters (HEH) and Hantzsch 4-aryl-1,4-dihydropyridines (4aryl-HEH) with the tropylium cation as a formal hydride acceptor were investigated. The observed kinetic isotope effect (KIE, k H /k D ), using HEH and 4,4-d 2 -HEH as substrates, was 4.16, sug
## Abstract Kinetic modeling of the lowβtemperature (typically __T__ β©½ 200Β°C) thermal aging of polymers is a problem of great technological importance, owing to the continuously increasing needs of industry in terms of reliable methods for lifetime prediction. In the temperature domain under consid