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Oxidation of Unsaturated Compunds. IV. Kinetics of the Reaction of Indene with Oxygen; Evidence of the Identity of Active Intermediates in Thermal and Catalyzed Oxidations

✍ Scribed by Russell, Glen A.


Book ID
126068361
Publisher
American Chemical Society
Year
1956
Tongue
English
Weight
496 KB
Volume
78
Category
Article
ISSN
0002-7863

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✍ George R. Smith; William A. Guillory πŸ“‚ Article πŸ“… 1977 πŸ› John Wiley and Sons 🌐 English βš– 970 KB

## Abstract The kinetics of the reaction of __cis__‐(NO)~2~ with solid oxygen to form __iso__‐N~2~O~4~ have been studied between 13 and 29 K. The overall reaction is pseudo first order in __cis__‐(NO)~2~, and solid oxygen serves both as a reactant and the matrix. The pseudo‐first‐order rate constan