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Oxidation of U(IV) by atmospheric oxygen in pH 1.5–7.4 aqueous solutions

✍ Scribed by V.P. Shilov; A.B. Yusov; V.F. Peretrukhin; C.H. Delegard; A.V. Gogolev; A.M. Fedosseev; L.P. Kazansky

Book ID: 116602118
Publisher: Elsevier Science
Year: 2007
Tongue: English
Weight: 474 KB
Volume: 444-445
Category: Article
ISSN: 0925-8388
DOI: 10.1016/j.jallcom.2007.02.082

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## Abstract To understand the chemistry of Cu(II)–NH~3~–S(IV)–O~2~ system, the kinetics of the oxidation of sulfur(IV) catalyzed by amminecopper(II) complexes has been studied in the ammonia‐buffered solutions. Sulfur(IV) is oxidized to sulfate. The complexes, Cu(NH~3~)^2+^, Cu(NH~3~)~2~^2+^, and C