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Oxidation of toluene linked with Ru(acac)3 catalysed electro-oxidation of water

โœ Scribed by M. Michman; M. Oron

Book ID
103067012
Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
475 KB
Volume
39
Category
Article
ISSN
0013-4686

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โœฆ Synopsis

AhstrrctXatalytic

electro-oxidation of water is linked with the oxidation of toluene. The catalyst, Ru(acac), acts as a reversible mediator. Controlled potential electrolysis of water with Ru(acac), at 1.35-1.5V in the presence of toluene, yields bitolyl and benzyltoluene in small amounts. Toluene coupling takes place at least 1 V below the overpotential for its direct electro-oxidation and is best explained as caused by electrogenerated radicals.

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