Oxidation of the triterpenic hopane skeleton by peracids
โ Scribed by Philippe Bisseret; Dominique Armspach; Serge Neunlist; Michel Rohmer
- Book ID
- 104228401
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- French
- Weight
- 249 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Treatment of bauerenyl acetate (2) with m-chloroperbenzoic acid at 4 ยฐC yielded the migrated pcoducls, viz. 7c~-hyckoxy-14,27-cycloisoursan-3[l-yl acetate (9) ~d its 15ยข~-hy&oxy derivative (12) belonging to a new skeleton, 7a-hydroxyisours-14-en-3[$-yl acetate (10) and 14ยขt,15c~-epoxy-7ct-hydcox~3~-
The 13C NMR assignments of ten triterpene hydrocarbons of the hopane group are presented. Assignments for eight of the hydrocarbons are reported for the first time, whilst revisions to the published assignments of hopane and 17a-hopane are described.