Oxidation of the CDE Rings of Pentacyclic Quinoline Compounds Derived from Tetrahydroalstonine
✍ Scribed by Cécile Dumas; Christiane Kan-Fan; Jacques Royer; Henri-Philippe Husson
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 312 KB
- Volume
- 2000
- Category
- Article
- ISSN
- 1434-193X
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✦ Synopsis
New polycyclic 8,9-dihydro-7H-indolizino[1,2-b]quinolin-11-ones have been synthesized from tetrahydroalstonine (2) through sequential oxidation reactions.
📜 SIMILAR VOLUMES
The recent paper 2) of Buchardt suggesting that the stable photo-products from 2-phenylquinoline l-oxides have the 4,5-hens-1,3-oxasepine structure (IB) rather than the oxaziridine structure (IA) prompted us to report the results of our study on this problem.
## Abstract Dioxygen‐sensitive dinuclear manganese complexes of the phenoxo‐hinged dinucleating ligand 2,6‐bis{[__N__,__N__′‐bis(2‐picolyl)amino]methyl}‐4‐__tert__‐butylphenolato (bpbp^–^) containing exogenous labile THF, water and perchlorato ligands are described. The manganese(II) complexes [Mn~