𝔖 Bobbio Scriptorium
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Oxidation of tetracyanonickellate (II) in the presence of organic cation

✍ Scribed by Dr. A. T. Oza

Book ID
102131771
Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
320 KB
Volume
24
Category
Article
ISSN
0232-1300

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✦ Synopsis

Oxidation of Tetracyanonickellate (11) in the Presence of Organic Cation A new material (TMPD),Ni(CN),Io.5 . H,O has been prepared (TMPD = N,N,N',N'tetramethyl-p-phenylenediamine). The solution and mull absorption spectra in the infrared range indicate the presence of the redox process TMPD+ + TMFD2+ and tetracyanonickellate (IV) units.

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## Abstract **BACKGROUD:** Direct oxidation of alkylaromatics to the corresponding aromatic ketone is an important process in the manufacture of perfumes, pharmaceuticals, flavors, dyes and agrochemicals. For example, tetralin is oxidized to produce 1‐tetralinone, which is a key intermediate in the