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Oxidation of some tris(2,2'-bipyridyl)- and tris(1,10-phenanthroline)osmium(II) salts by thallium(III) in aqueous acid

โœ Scribed by Nord, Gwyneth.


Book ID
127017561
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
635 KB
Volume
15
Category
Article
ISSN
0020-1669

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Luminescent metal complexes. 4โ€”13C NMR s
โœ Michael J. Cook; Anthony P. Lewis; Glenn S. G. McAuliffe ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 598 KB

C Chemical shifts are reported for the ruthenium(II) tris complexes of thirteen 2,Z-bipyridyls and three 1,lO-phenanthrolines and for the osmium(]") bris complexes of five 2,2'-bpyridyls. Chelation induced shifts -&3 are discussed in terms of models for n back-bonding. -C NMR is shown to be a conven