Mechanism of oxidation of triphenylphosp
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C. Srinivasan; K. Pitchumani
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Article
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1982
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John Wiley and Sons
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English
⚖ 456 KB
The kinetics of oxidation of triphenyl derivatives of group V elements Ph3M (M = P, As Sb) by potassium peroxodisulfate have been investigated spectrophotometrically in 60% acetonitrile-40% water (v/v) mixture. The reaction follows second-order kinetics, first order in each reactant. Changes in the