𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Oxidation of phenols with hydrogen(hexacyanoferrate(III))

✍ Scribed by L. Taimr; J. Pospíšil

Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
109 KB
Volume
12
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Kinetics of oxidative coupling of phenol
Kinetics of oxidative coupling of phenols: Oxidation of naphthols by alkaline hexacyanoferrate (III)
✍ Mitra Bhattacharjee; M. K. Mahanti 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 English ⚖ 282 KB

## Abstract The oxidation of naphthols by alkaline hexacyanoferrate(III), at constant ionic strength, gave coupled products. The rate of the reaction was dependent on the first powers of the concentrations of substrate, oxidant, and alkali. The activation energies were 31.8 and 34.5 kJ/mol for α na

Oxidative coupling of 4,5,6-trichlorogua
Oxidative coupling of 4,5,6-trichloroguaiacol with iron(III) hexacyanoferrate(III)
✍ Kristina C. Arnoldsson; Carl Axel Wachtmeister 📂 Article 📅 1991 🏛 Elsevier Science 🌐 French ⚖ 249 KB

Iron(lll) hexacyanoferrate(lll) is shown to be a useful reagent in oxidative coupling of 4,5,5,. Dimerisation proceeds via oxidative demethylation and loss of chloride to give an orrho-quinonoid dimer in high yield. The proposed structure 1 is based largely on mass-spectra of methyl derivatives of t

Oxidation of cyclic ketones by alkaline
Oxidation of cyclic ketones by alkaline hexacyanoferrate(III) catalyzed by rhodium(III)
✍ Praveen K. Tandon; Mamta Dhusia; Sumita Sahgal 📂 Article 📅 2009 🏛 Elsevier Science 🌐 English ⚖ 440 KB

The kinetics of the reaction between cyclopentanone and cyclohexanone with hexacyanoferrate(III) ion catalyzed by rhodium(III) chloride in alkaline medium has been investigated at four temperatures. The data show that the reaction follows first order kinetics with respect to hydroxide ion and cyclic