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Oxidation of phenols by molecular oxygen catalysed by transition metal complexes. Comparison between the activity of various cobalt and manganese complexes and the role of peroxy intermediates

✍ Scribed by Frostin-Rio, Maryvonne; Pujol, Dani�le; Bied-Charreton, Claude; Perr�e-Fauvet, Martine; Gaudemer, Alain

Book ID
118153538
Publisher
Royal Society of Chemistry
Year
1984
Weight
991 KB
Volume
0
Category
Article
ISSN
1472-7781

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Radical reactions in the co-ordination field of transition metals. VIII—σ-phenoxy and σ-cyclohexadienoneoxy radicals co-ordinated to cobalt (III) and their generation by tert-butylperoxy radicals or by molecular oxygen complexed to cobalt
✍ A. Tkáč; L. Omelka 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 English ⚖ 975 KB

## Abstract The formation of a ternary complex between phenols, Co (II)‐acetylacetonate and molecular oxygen has been established at ambient temperature and in non‐polar solvents. After intramolecular electron transfer the transient magnified image radical enhances the homolytic scission of the O