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Oxidation of organic sulphides - XII: Oxidation of phenyl methyl sulphoxides in aqueous alkaline solution by peroxybenzoic acid

✍ Scribed by R. Curci; G. Modena

Publisher
Elsevier Science
Year
1965
Tongue
French
Weight
222 KB
Volume
6
Category
Article
ISSN
0040-4039

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✦ Synopsis

In recent papers the first example of oxidation of sulphoxides in alkaline medium with peroxybenzoic acid has been reportedl.

The reaction was studied in dioxane-water as solvent in the (apparent) pH range 4-12 . Contrary to sulphides, amine, etc., sulphoxides, or at least those considered2, reacted faster in alkali ne than in neutral or acidic medium. The pH in the ranges 4-7 and lo-12 dia not significantly affect the rates while the velocity was strongly increased in the range 7-10.

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## Abstract The kinetics and mechanism of the silver(II) oxidation of methanol, ethanol, 1‐propanol, 1‐methyl‐ ethanol, 1‐butanol, 2‐methyl‐1‐propanol, 2‐butanol, 2‐methyl‐2‐propanol, D~4~‐methanol, and D~6~‐methanol have been investigated at 8.0 and 20.0°C in aqueous perchloric acid media (1.00 ≤