## Abstract The kinetics of oxidation of some monosaccharides viz., Dโribose, Dโxylose, and Dโarabinose, Dโglucose, Dโfructose, Dโgalactose, 2โdeoxyglucose, and ฮฑโmethyl glucopyranoside by MnO~4~^2โ^ in aqueous alkaline medium have been studied. The rate of oxidation has been found to be firstโorde
Oxidation of nucleic acid bases by hexavalent manganese in aqueous alkaline medium: a kinetic study
โ Scribed by Koya Venkateswara Rao; Mundra Adinarayana
- Publisher
- Springer
- Year
- 1992
- Tongue
- English
- Weight
- 288 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0340-4285
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๐ SIMILAR VOLUMES
Kinetics of oxidation of fumarate, acrylate, cinnamate, and maleate anions by hexavalent manganese has been studied in aqueous alkaline medium. The order in [oxidant] was unity while that in [substrate] was fractional. The order of reactivity of anions is fumarate -+ acrylate --f cinnamate + maleate
The kinetics of oxidation of 1,4-Dioxane (Dio) by Diperiodatonickelate (IV) (DPN) in aqueous alkaline medium at a constant ionic strength of 1.5 mol dm ฯช3 was studied spectrophotometrically. The reaction shows first-order kinetics in [DPN] and less than unit order dependence each in [Dio] and [OH ฯช
Manganese(III) acetate was prepared by the electrolytic oxidation of Mn(OAc)2 in aqueous AcOH. The electrogenerated manganese(III) species was characterised by spectroscopic and redox potential studies. The kinetics of oxidation of pyridoxine (PRX) by manganese(III) in aqueous AcOH were investigated