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Oxidation of Norditerpenoid Alkaloids with Osmium Tetroxide

โœ Scribed by Desai, Haridutt K.; Chokshi, Hitesh P.; Pelletier, S. William

Book ID
126061629
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
455 KB
Volume
52
Category
Article
ISSN
0163-3864

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High levels of asymmetry can be achieved in the osmium tetroxide cis-hydroxylation of olefins by employing (-)-(R,R)-N,N,N',N'-tetramethylcyclohexane-l,2-traos-diamine as a chiral ligand for the osmium. Osmium tetroxide oxidation of olefins is an excellent method for forming vicinal diols under mil