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Oxidation of non-activated CH bonds in hydrocarbons and steroids

✍ Scribed by T. Linz; H.J. Schäfer

Publisher: Elsevier Science
Year: 1987
Tongue: French
Weight: 101 KB
Volume: 28
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)96918-1

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✦ Synopsis

Cr03 in CH2C12/CH3COOH/(CH3CO)20 oxidizes hydrocarbons to alcohols and ketones, Sa-androstane and 36-acetoxy-5a-androstane are converted to 5a-androst-14-en-16-ones.

Regioselective oxidations of C-H bonds are desirable for the economic ' J.

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