Oxidation of N,N-Dialkyl Hydroxylamines with t-Butyl Hydroperoxide. A New Synthesis for Nitrones
โ Scribed by Mare, H. E. De La; Coppinger, G. M.
- Book ID
- 127075228
- Publisher
- American Chemical Society
- Year
- 1963
- Tongue
- English
- Weight
- 378 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Oxidation ofN, N-disubstituted hydroxylamines to nitrones catalyzed by the Jacobsen catalyst occurs cleanly in the presence of hydrogen peroxide, sodium hypochlorite or iodosylbenzene as the stoichiometric oxidant. Meso 3,4-cis-isopropylidenedioxy-1hydroxypyrrofidine gave the corresponding protected
## Oxidation of Hydroxylamines to Nitrones Catalyzed by (Salen)Mn(III) Complexes. Enantioselective Synthesis of a Protected cis-Dihydroxypyrroline N-Oxide with Jacobsen Catalyst. -The Jacobsen salen catalyst is found to catalyze efficiently the oxidation of N,N-disubstituted hydroxylamines (I) t