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Oxidation of N-benzyl groups

✍ Scribed by Wen-Ge Qiu; Shu-Sen Chen; Yong-Zhong Yu

Publisher: John Wiley and Sons
Year: 2010
Tongue: English
Weight: 218 KB
Volume: 18
Category: Article
ISSN: 0256-7660
DOI: 10.1002/cjoc.20000180518

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✦ Synopsis

Abstract

The additive reactivity of 2,6,8,12‐tetraacetyl‐4, 10‐dibenzyl‐2,4,6,8,10,12‐hexazatetracyclo [5.5.0.0^5.9^. 0^3.11^] dodecane (3) in several conditions was studied. It was found that the N‐benzyl groups in compound 3 could be oxidized to benzoyl groups by Cr(VI) reagents, and could be removed by cerium ammonium nitrate (CAN), meanwhile nitroamine products were given.

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