Oxidation of methyl phenyl sulfide with molecular oxygen in the presence of isobutyraldehyde and transition metal monosubstituted heteropolytungstates
β Scribed by Khavrutskii, I. V. ;Maksimov, G. M. ;Kholdeeva, O. A.
- Book ID
- 105589064
- Publisher
- Springer
- Year
- 1999
- Tongue
- English
- Weight
- 292 KB
- Volume
- 66
- Category
- Article
- ISSN
- 0133-1736
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Multi-metallic hydrotalcites consisting of magnesium, aluminum, and iron, or copper elements were prepared, which catalyzed the Baeyer-Villiger oxidation using a combination system of molecular oxygen and benzaldehyde. In particular, the Mg-Al\(\mathrm{Fe}-\mathrm{CO}_{3}\) hydrotalcite efficiently
## Abstract The epoxidation of methyl oleate with molecular oxygen in the presence of aldehydes was investigated and optimized. Epoxide yields up to 99% were observed in organic solvents. The preponderant radical reaction was started by a single organic radical chain initiator, without using a meta