## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
Oxidation of Matrix-Isolated Silylenes
β Scribed by Wolfram Sander; Holger F. Bettinger; Holger Bornemann; Martin Trommer; Magdalene Zielinski
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 7 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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Vinyl-substituted silylenes, 2,5-bis(methylene)-l -silacyclopentane-l ,l -diyl (1) and 2-methybne-1 -silacyclopentane-1 ,I -diyl (2), generated photochemically from the corresponding trisilanes in 3-methylpentane (3-MP) at 77 K, showed broad bands at 505 and 475 nm, respectively, which were assigned
Flash pyrolysis of 1,1-diethynyl-2,2,2-trimethyldisilane ( ) butadiynylsilylene ( ). The identification of these reactive intermediates is based on the comparison between the and triethynylsilane (18) led to the formation of two silylenes of the elemental composition C 4 H 2 Si, namely dieth-experim