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Oxidation of limonene catalyzed by MnIII(Salen)Cl-H2O

✍ Scribed by Maria Fátima Teixeira Gomes; O. A. C. Antunes

Book ID
112412709
Publisher
Springer US
Year
1996
Tongue
English
Weight
182 KB
Volume
38
Category
Article
ISSN
1011-372X

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Kinetics and mechanism of oxidation of aryl methyl sulfoxides with (salen)MnIII/H2O2 catalytic system
✍ Arunachalam Chellamani; Paramasivan Sengu; Naina Mohamed Ismail Alhaji 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 413 KB

The kinetics of (salen)Mn III complexes-catalysed oxidation of aryl methyl sulfoxides with hydrogen peroxide in 80% acetonitrile-20% water solvent mixture at 25 • C has been followed spectrophotometrically. The reaction is first-order in (salen)Mn III , zero-order in hydrogen peroxide and fractional