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Oxidation of homoallyl alcohols

โœ Scribed by I. A. Korshevets; E. A. Mistryukov


Book ID
112444511
Publisher
Springer
Year
1986
Tongue
English
Weight
329 KB
Volume
35
Category
Article
ISSN
1573-9171

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Diastereoselective cycloadditions of chi
โœ Martin G. Kociolek; Chayanant Hongfa ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 76 KB

The first diastereoselective cycloaddition of a nitrile oxide with a homoallylic alcohol is discussed. The reaction of benzonitrile oxide with the magnesium alkoxides of chiral homoallylic alcohols has been shown to proceed with good diastereoselectivity, favoring the syn isomer of the resulting 2-i