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Oxidation of Hindered Phenols. VII. Solvent Effects on the Disproportionation of Certain Phenoxy Radicals

โœ Scribed by Cook, Clinton D.; Norcross, Bruce E.

Book ID
120284281
Publisher
American Chemical Society
Year
1959
Tongue
English
Weight
571 KB
Volume
81
Category
Article
ISSN
0002-7863

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Effect of solvent viscosity on the kinet
Effect of solvent viscosity on the kinetics of reversible dimerization of phenoxy radicals
โœ P. P. Levin; I. V. Khudyakov; V. A. Kuzmin ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 577 KB

Flash photolysis technique has been used to obtain the rate and thermodynamic parameters of the reversible dimerization reactions of a range of ten phenoxy radicals (I-X) in a toluene-dibutylphthalate mixture (0.6 CP < TJ < 18.4 cF): The main reason for the difference in the k l values are the diff