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Oxidation of hexaaquoiron(II) by periodate in aqueous acidic solution

โœ Scribed by Foud R. El-eziri; Yousif Sulfab


Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
26 KB
Volume
34
Category
Article
ISSN
0020-1693

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๐Ÿ“œ SIMILAR VOLUMES


Oxidation of hexaaquoiron(II) by perioda
โœ Fouad.R. El-Eziri; Yousif Sulfab ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 429 KB

The oxidation of Fe(H) by periodate in aqueous acidic solutions obeys the rate law (i) ## Rate = {k, + k,/[fl]} [Fe(H)]' + kk'[Wll)l W-IT WI + k3 [Wll)l 2 [L-l T where [L61T represents the total periodate concentration. The magnitudes of k,,, k;, ky and k3 are 0.235 set-', 120 set-', 7.5 f 1.5 set-

Oxidation of ethylenediaminetetraacetato
โœ Ahmad Y. Kasim; Yousif Sulfab ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 333 KB

The kinetics of oxidation of CoEDTA2-by periodate follow the rate law (i) Rate = k&l [CoEDTA2-I F-1 1 +Kl[L-] Where [L-l is the total periodate concentration, k3 is the rate constant for the electron-transfer process, and K, is the pre-equilibrium formation constant. Activation parameters are report

Photo-oxidation of tris(2,2'-bipyridine)
โœ Oleg V. Gerasimov; Valentin N. Parmon; Sergei V. Lymar ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 962 KB

Thermal and photochemical oxidations of Fe(bpy)sz+ (bpy=2,2'-bipyridine) by the periodate anion IO,-in acidic aqueous solution were studied. For the thermal process, the rate-limiting step is monomolecular dissociation of the iron(D) complex preceding the fast oxidation by IO,-. Photo-oxidation of F