The anodic oxidation of the cyanide ion at a platinum electrode in aqueous solution was observed by polarization modulation infrared reflection absorption spectroscopy( PM IRRAS). The cyanide ion was adsorbed on the electrode surface in the potential region more negative than 0.4 V (versus Ag/AgCI).
โฆ LIBER โฆ
Oxidation of HCHO and CH3OH on a pt electrode studied by polarization modulation infrared spectroscopy
โ Scribed by Fusao Kitamura; Machiko Takahashi; Masatoki Ito
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 334 KB
- Volume
- 123
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
Infrared spectra of adsorbed CO decomposed from HCHO and CH,OH under a constant electrode potential were observed. Oxidation processes of HCHO and CH,OH and the frequency shifts of adsorbed CO are discussed.
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The reconstruction process on a clean Pt ( 110) surface was monitored by infrared reflection absorption spectra of CO on the surface. The adsorbate-induced phase transition from the (1 x2 )-Pt (110) to the ( I x I )-Pt( 110) structure was completely suppressed under negative electrode potentials. Th