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Oxidation of fatty alcohols to acids in the caecum of a gourami (Trichogaster cosby)

✍ Scribed by K. Thyagarajan; Donald M. Sand; Howard L. Brockman; Hermann Schlenk


Book ID
115737772
Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
744 KB
Volume
575
Category
Article
ISSN
0005-2760

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A novel CrO~ catalyzed oxidation of primary alcohols to the carboxylic acids is reported. The oxidation proceeds smoothly with only 1-2 tool % of CrO 3 and 2.5 equivalents of H~IO 6 in wet MeCN to give the carboxylic acids in excellent yield. No significant racemization is observed for alcohols with