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Oxidation of Diazo Compounds with Singlet Oxygen. Formation of Ozonides

✍ Scribed by Higley, D.; Murray, R.


Book ID
125935346
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
373 KB
Volume
96
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES


Singlet oxygen oxidation of pyrroles. Fo
✍ Harry H. Wasserman; Mingde Xia; Jianji Wang; Anders K. Petersen; Michael Jorgens πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 206 KB

The ten-butyl ester of 3-methoxy-2-pyrrolecarboxylic acid 3 undergoes reaction with singlet oxygen to form an intermediate imino hydroperoxide 4. This hydroperoxide may be trapped by a variety of nucleophiles yielding 5substituted pyrroles 6. With strong nucleophilic substituents at the 5-position,