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Oxidation of Cyclopropylidenes with Ozone and (Singlet) Oxygen

✍ Scribed by A. Hofland; Th. J. De Boer; H. Steinberg

Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
46 KB
Volume
91
Category
Article
ISSN
0037-9646

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chain reaction already accepted in the case of other bicy-cl~[l.l.O]butanes[~~. Why does the phenylthio radical attack benzvalene (1) at the double bond but homobenzvalene (8) at the bicy-clot1 .I .O]butane system? Since thio radicals have electrophilic characterf7I, the interaction with the HOMO o