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Oxidation of Cyclohexane Catalyzed by TS-1 in Ionic Liquid with Tert-butyl-hydroperoxide

โœ Scribed by Jianying WANG; Hua ZHAO; Xiangjing ZHANG; Runjing LIU; Yongqi HU


Book ID
114338085
Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
206 KB
Volume
16
Category
Article
ISSN
1004-9541

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Oxidation of alkynes into conjugated ace
โœ Jacques Muzart; Olivier Piva ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 241 KB

Using LBuOOH with catalytic amounts of CrOg and TsOH, regioselective a-oxidation of alkynes to conjugated ynones was observed at room temperature with yields superior to those of stoichiometric chromium procedures. Yields were slighty decreased in the absence of p.toluenesulfonic acid. Chromium"' o