The molar enthalpies of solution of \(\mathrm{Cs}_{2} \mathrm{MnO}_{4}\) in \(\left(4.032 \mathrm{~mol} \cdot \mathrm{dm}^{-3} \mathrm{H}_{2} \mathrm{SO}_{4}+0.106 \mathrm{~mol} \cdot \mathrm{dm}^{-3}\right.\) \(\left.\mathrm{FeSO}_{4}\right), \mathrm{Cs}_{2} \mathrm{Si}_{4} \mathrm{O}_{9}\) in \(0.
Oxidation of CS2 by AsBr4+: The Unexpected Formation of the Simple CS2Br3+ Carbenium Ion
β Scribed by Marcin Gonsior; Ingo Krossing
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 224 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0947-6539
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Reaction of 2 with CO in the presence of nBuLi: 2 (200 mg, 0.22 mmol) in THF (30 mL) was treated at -78Β°C with 0.3 mL (0.48 mmol) of an nBuLi solution (1.6 M in hexane). The deeo red solution was stirred under CO for 10 min at room temperature and then treated with 5 mL of MeOH After evaporation of