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Oxidation of bis-aroylhydrazones of 3,3-dimethylpentane-2,4-dione and thermal decomposition of the oxidation products

✍ Scribed by J. Stephanidou-Stephanatou


Book ID
112127144
Publisher
Journal of Heterocyclic Chemistry
Year
1983
Tongue
English
Weight
412 KB
Volume
20
Category
Article
ISSN
0022-152X

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The liquid-phase oxidation of 2,4-dimeth
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The initiated oxidation of 2,4dimethylpentane in the neat liquid phase at 100Β°C with 760 torr 0 gives more than 90% of a mixture of 2,4-dihydroperoxy-2,4-dimethylpentane and 2-hydroperoxy-2,4-dimethyIpentane in a ratio of 7 : 1. The rate of oxidation depends closely on the [initiator]"\*, consistent