Oxidation of aromatic bis-amides by thallium (III) trifluoroacetate

✍ Scribed by K.S.Y. Lau; D.I. Basiulis

• Book ID: 104241462
• Publisher: Elsevier Science
• Year: 1981
• Tongue: French
• Weight: 223 KB
• Volume: 22
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(01)90267-9

✦ Synopsis

Aromatic 1, 2-bisamides undergo thallium (III) promoted oxidative intramolecular cyclization to generate new 5-membered heterocyclic rings. Formation of para-quinone was shown to be a minor pathway in one case.

92, 3520 (1970).