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Oxidation of Aqueous Polyselenide Solutions. A Mechanistic Pulse Radiolysis Study

✍ Scribed by Goldbach, Andreas; Saboungi, Marie-Louise; Johnson, J. A.; Cook, Andrew R.; Meisel, Dan


Book ID
126205308
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
73 KB
Volume
104
Category
Article
ISSN
1089-5639

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The one-electron oxidation of sulphacetamide by specific oxidizing radicals such as N;, Br; , Cl;, T12+ and SOT in the pH range 2-9.2 has been studied employing pulse radiolysis technique. The semi-oxidized species formed exhibits a pK, at pH 5.4 indicating the presence of two conjugate acid-base fo