Cyclohexene was oxidized to 2-cyclohexen-1-ol and 2-cyclohexen-1-one by atmospheric pressure of molecular oxygen in the presence of linear polystyrene-bound-2,29-bipyridine-ruthenium complexes in the absence of solvent at 70658C selectively. The alcohol / ketone molar ratio of the products can be ad
Oxidation of alkylbenzenes catalyzed by polymer-bound 2,2′-bipyridine-iron complexes
✍ Scribed by Zi-Qiang Lei; Yun-Pu Wang
- Publisher
- Elsevier Science
- Year
- 1992
- Weight
- 264 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0923-1137
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Thermal and photochemical oxidations of Fe(bpy)sz+ (bpy=2,2'-bipyridine) by the periodate anion IO,-in acidic aqueous solution were studied. For the thermal process, the rate-limiting step is monomolecular dissociation of the iron(D) complex preceding the fast oxidation by IO,-. Photo-oxidation of F
Polymer-bound 2,29-bipyridine-iron(II,III) complexes have been shown catalytically oxidize cyclic alkenes with atmospheric pressure of molecular oxygen or air in the absence of solvent at | 708C. When cyclohexene are oxidized, the double bonds are maintained and 2-cyclohexen-1-ol as well as 2-cycloh
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