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Oxidation of alkyl trimethylsilyl ketene acetals with lead(IV) carboxylates

✍ Scribed by Rubottom, George M.; Gruber, John M.; Marrero, Roberto; Juve, Henrik D.; Kim, Chong Wan


Book ID
126450814
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
671 KB
Volume
48
Category
Article
ISSN
0022-3263

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Lead (IV) acetate oxidation of unsaturat
✍ Robert M. Moriarty; Harold G. Walsh; Harsh Gopal πŸ“‚ Article πŸ“… 1966 πŸ› Elsevier Science 🌐 French βš– 190 KB

Lead tetraacetate oxidation of saturated carboxylic acids causes decarboxylatioq with formation of the corresponding lower acetate and alkene' . Koch1 \*2 has presented excellent evidence in support of a free rodica' chain mechanism for the oxidative decarboxylation. In the case of certain unsaturat