Oxidation of aliphatic alcohols by triethylammonium chlorochromate in non-aqueous medium – A kinetic and mechanistic study
✍ Scribed by Mansoor, S. Sheik; Shafi, S. Syed
- Book ID
- 121938752
- Publisher
- Elsevier
- Year
- 2014
- Tongue
- English
- Weight
- 540 KB
- Volume
- 7
- Category
- Article
- ISSN
- 1878-5352
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract The oxidation of glycolic, lactic, malic, and a few substituted mandelic acids by tetraethylammonium chlorochromate (TEACC) in dimethylsulfoxide leads to the formation of corresponding oxoacids. The reaction is first order each in TEACC and hydroxy acids. Reaction is failed to induce th
## Abstract The kinetics of oxidation of some monosaccharides viz., D‐ribose, D‐xylose, and D‐arabinose, D‐glucose, D‐fructose, D‐galactose, 2‐deoxyglucose, and α‐methyl glucopyranoside by MnO~4~^2−^ in aqueous alkaline medium have been studied. The rate of oxidation has been found to be first‐orde