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Oxidation of a Water-Soluble Phosphine and Some Spectroscopic Probes with Nitric Oxide and Nitrous Acid in Aqueous Solutions †

✍ Scribed by Bakac, Andreja; Schouten, Margaret; Johnson, Alicia; Song, Wenjing; Pestovsky, Oleg; Szajna-Fuller, Ewa


Book ID
126836295
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
822 KB
Volume
48
Category
Article
ISSN
0020-1669

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The dark reaction of NO, and HzO vapor in 1 atm of air was studied for the purpose of elucidating the recently discussed unknown radical source in smog chambers. Nitrous acid and nitric oxide were found to be formed by the reaction of NO2 and H2O in an evacuable and bakable smog chamber. No nitric a