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Oxidation of 3-carene with mercuric acetate

โœ Scribed by Z. G. Isaeva; B. A. Arbuzov; V. V. Ratner; I. P. Povodyreva


Book ID
112420286
Publisher
Springer
Year
1965
Tongue
English
Weight
618 KB
Volume
14
Category
Article
ISSN
1573-9171

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Secondary allylic acetates are the almost exclusive kinetically-controlled products formed in the oxidation of both l-and 2-olefins by Hg(OAcj2 in AcOH.~ Ape& of equilibrating primary and secondary allylic mercuric acetates, with the equilibrium being overwhelmingly on the side of the former were su